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Bernard Nysten
Full Professor @ UCLouvain

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Nanomechanics

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By Admin_bnysten, 19 December, 2022

Using various SPM-based methods, we were and are studying the local mechanical properties of polymer blends, nanocomposites, and nanomaterials. First, we developed expertise in force-curve measurement and force modulation microscopy (FMM) to locally measure and map the elastic and viscoelastic properties of polymers and polymer blends. Then, in the frame work of the PhD thesis of Stéphane Cuenot, we developed the "Resonant Contact-AFM" (Resonant C-AFM) method that allowed us measuring the elastic modulus of polymer and metallic nanowires and nanotubes and characterising the elastic modulus gradient in polymer blends. Presently, we are extensively using modes such as HarmoniX®, PFT-QNM® and force-volume to study the local properties in polymer blends, composites and nanocomposites, especially at the interfaces.

FMM on PP/EP blend
Force modulation microscopy: topography, rigidity and loss tangent maps obtained on toughened polypropylene (see J. Appl. Phys. 1995, 78, 5953)
PPy nanotube dflection
Resonant contact AFM: size effect on the elastic modulus of suspended polypyrrole nanotubes (see Phys. Rev. B 2004, 69, 165410)
CR-AFM on polymer blend
esonant C-AFM: rigidity gradient at the interface in a polybutylene terephthalate based polymer blend (see Nysten B., HEFQ thesis, 2007)
Harmonix AFM on PP/EP blend
HarmoniX mode: topography, modulus, adhesion, dissipation and phase images obtained on toughened polypropylene (Barhami A., Master thesis, UCLouvain)
PFT-QNM AFM on Phenoxy-CSR mixture
PeakForce Tapping QNM: DMT modulus and adhesion images obtained on core-shell rubber particles embedded in epoxy resin (see Polymer 2019, 165, 180)
PFT-QNM AFM on epoxy/phenoxy blend
PeakForce Tapping QNM: topography and DMT modulus images obtained on epoxy/polyphenoxy blends (see Polymer 2019, 165, 180)

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